Research
Projects:
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Knots and entanglements are
common features observed on filaments
or fibrous materials. The difficulty
of writing down an entanglement
constraint comes from its global
character. This subject is the source
of a large literature in mathematics
and in physics.
We have analyzed he
properties of stiff knots, i.e.
knotted strings whose shape is
dictated by the bending curvature
energy. Stiff knots, such as loose
knots with nylon strings, are ordinary
objects in everyday life. An upsurge
of interest in stiff knots recently
came from studies which pertain
to biology and
nano-technologies, such as knots with
actin filaments, nanotubes, nanotube
fibers, and silica wires. These
studies point out the wide relevance
of stiff knots for the experimental
determination of the bending rigidity,
knot induced polymer and filament
break-up, or nano-manipulation.
Furthermore, knots may also
be seen as elementary entanglements
which capture some basic mechanical
and geometrical properties of complex
entangled structures. Stiff knots thus
provide insights for the curvature
energy dominated behavior of tightly
entangled semi-flexible polymers and
other fibrous materials.
Using some relevant
topolgical knot invariant, we have
obtained rigourous inequalitites for
the knot energy. In the limit of thin
string widths, we have identified a
general phenomenon called braid
localization. These results were
confirmed with the help of Monte Carlo
Simulations.
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Zero-temperature lowest energy
conformation of stiif knotted filaments
(Kinetic Monte Carlo, Simulated annealing)
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